BK1064-ch47_R2_250706 PREDICTION OF CO2 AND H2S SOLUBILITY IN AQUEOUS MDEA SOLUTIONS USING AN EXTENDED KENT AND EISENBERG MODEL

Gas sweetening, the removal of acid gases (H2S and CO2) by absorption in aqueous alkanolamine solutions, is an important gas treatment operation. Methyldiethanolamine (MDEA) is widely employed for gas sweetening, because of its high absorption capacity and flexibility to meet process requirements. For process simulation or design, realistic predictions of acid gas solubilities in MDEA solutions are needed. In the context of flowsheet synthesis, design and optimisation, a reliable model that is simple to use and reasonably accurate is required. This paper presents a new model for the prediction of solubilities of both H2S and CO2 in aqueous MDEA solutions. The model extends the Kent and Eisenberg (1976) model, which was developed for primary and secondary amines. Model predictions are validated against experimental data for both single and mixed acid gas systems. The applicability of the model is further demonstrated by comparing flowsheet simulation results and plant data for commercial units operating over a wide range of conditions.